CH4－CO2重整反应动力学机理与催化剂的改良
CH4-CO2 Reforming Reaction Dynamics Mechanism and Catalyst Reformation
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- 引用格式:
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龙,威,徐文媛.CH4－CO2重整反应动力学机理与催化剂的改良[J].天然气与石油,2011,29(1):0.doi:
.CH4-CO2 Reforming Reaction Dynamics Mechanism and Catalyst Reformation[J].Natural Gas and Oil,2011,29(1):0.doi:
- DOI:
- 作者:
- 龙 威 徐文媛
- 作者单位:
- 华东交通大学化学化工系
- 关键词:
- 甲烷二氧化碳重整；催化剂；反应机理；失活；助剂；积炭
Methane and carbon dioxide reforming； Catalyst； Reaction mechanism； Deactivation； Adjuvant； Carbon deposit
- 摘要:
- 甲烷－二氧化碳重整反应是当代研究的热点，重整的微观反应动力学机理解决了已有的分歧。催化剂的选择、载体效应、助剂效应和抗积炭性能是影响反应的重点因素，通过对实验中催化剂的微观表征，分析比较并重点解决催化剂因积炭而失活的问题，其中包括对活性中心、载体、助剂等方面进行了大量的改进和拓展。
Methane and carbon dioxide reforming reaction is a contemporary research hotspot，microscopic reforming reaction dynamics mechanism has compensated for existing controversial differences. Selection of catalysts，carrier effect，adjuvant effect and anti-carbon de-position property are the key factors affecting the reaction. Through microcosmic characterization of catalyst in experiment，comparatively analyzed and resolved is the catalyst deactivation due to carbon deposit and largely improved and expanded are the activity center，carrier and adjuvant.
