CO2驱地面采输系统缓蚀阻垢剂优选研究
Study on corrosion and scale inhibitor selection for surface production and transportation system of CO2 flooding
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- 引用格式:
-
张洲,易勇刚,同航,张新,曾德智.CO2驱地面采输系统缓蚀阻垢剂优选研究[J].天然气与石油,2021,39(3):88-94.doi:10.3969/j.issn.1006-5539.2021.03.014
ZHANG Zhou , YI Yonggang , TONG Hang , ZHANG Xin , ZENG Dezhi.Study on corrosion and scale inhibitor selection for surface production and transportation system of CO2 flooding[J].Natural Gas and Oil,2021,39(3):88-94.doi:10.3969/j.issn.1006-5539.2021.03.014
- DOI:
- 10.3969/j.issn.1006-5539.2021.03.014
- 作者:
- 张洲1 易勇刚2 同航3 张新3 曾德智3
ZHANG Zhou1 , YI Yonggang2 , TONG Hang3 , ZHANG Xin3 , ZENG Dezhi3
- 作者单位:
- 1. 中国石油工程建设有限公司西南分公司,2. 中国石油新疆油田分公司工程技术研究院, 3. 油气藏地质及开发工程国家重点实验室•西南石油大学
1. CPECC Southwest Company, Chengdu, Sichuan, 610041, China; 2. Engineering Research Institute of PetroChina Xinjiang Oilfield Branch, Karamay, Xinjiang, 834000, China; 3. State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan, 610500, China
- 关键词:
- 采输系统;CO2;腐蚀结垢;缓蚀阻垢剂
Production and transportation system; Carbon dioxide; Corrosion and scaling; Corrosion and scale inhibitor
- 摘要:
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CO2驱提采技术因其诸多优点得到了广泛应用,但同时也带来了严重的地面采输系统腐蚀结垢风险。为此,分别采用电化学测试方法和静态阻垢法对油田常用的缓蚀剂和阻垢剂进行筛选,对优选的缓蚀剂和阻垢剂进行配伍性和协同性测试后,复配出效果优异的复合缓蚀阻垢剂,最后采用失重法和模拟工况阻垢率测试评价复合缓蚀阻垢剂的综合防护性能。筛选出的缓蚀剂和阻垢剂在55 ℃、常压下,饱和CO2的模拟地层水中对采输系统典型钢材20钢的缓蚀率达93.06%,阻垢率达95.18%;将筛选的缓蚀剂和阻垢剂复配后,在模拟工况下,复合缓蚀阻垢剂加量500 mg/L时20钢的腐蚀速率控制在0.045 mm/a以内,阻垢性能满足油田控制指标。研究结果表明,复配的复合缓蚀阻垢剂对CO2驱地面采输系统具有较好的防护作用,能保证其安全运行和生产。
The EOR technology of CO2 flooding is increasingly used because of its advantages, but it is also accompanied by the high risk of corrosion and scaling in the surface production and transportation system. As a result, this study was carried out using the electrochemical test method and the static scale inhibition method to evaluate and select corrosion and scale inhibitors commonly found in oil field. After the compatibility and synergy test of the corrosion and scale inhibitor, the most effective compound inhibitor was prepared. Finally, the comprehensive protection performance of the compound inhibitor was evaluated by weight loss method and scale inhibition rate test under simulated condition. The experimental results showed that: the corrosion inhibition rate of the selected corrosion inhibitor and scale inhibitor in the simulated formation water of saturated CO2 at 55 ℃ and atmospheric pressure is 93.06% and scale inhibition rate is 95.18% for the typical 20 steel used in the production and transportation system. After mixing together the selected corrosion inhibitor and scale inhibitor, the corrosion rate of the 20 steel is controlled within 0.045 mm/a when the amount of the composite corrosion and scale inhibitor is injected at 500 mg/L under the simulated condition. The scale inhibition rate is 93.91%, which can meet the performance indicators of oil field. The results showed that the compound corrosion and scale inhibitor can play a good role in protecting the production and transportation system of CO2 flooding facilities, and guarantee the safe operation and production activities.