含硫气田恶臭硫化物性质及阈限值研究
Study on Properties and Threshold Limit Values of Odor Sulfide in Sour Gas Field
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- 引用格式:
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戴万能,高晓根,计维安,肖黄飞,刘启聪.含硫气田恶臭硫化物性质及阈限值研究[J].天然气与石油,2015,33(6):0.doi:
Dai Wanneng, Gao Xiaogen, Ji Weian, Xiao Huangfei, Liu Qicong.Study on Properties and Threshold Limit Values of Odor Sulfide in Sour Gas Field[J].Natural Gas and Oil,2015,33(6):0.doi:
- DOI:
- 作者:
- 戴万能 高晓根 计维安 肖黄飞 刘启聪
Dai Wanneng, Gao Xiaogen, Ji Weian, Xiao Huangfei, Liu Qicong
- 作者单位:
- 中国石油西南油气田公司天然气研究院
Research Institute of Natural Gas Technology, PetroChina Southwest Oil & Gas Field Company
- 关键词:
- 恶臭;硫化物;职业接触;阈限值
Odor; Sulfide; Occupational exposure; Threshold limit value
- 摘要:
- 含硫气田的恶臭气体不仅污染环境,还可能对工作人员的身心健康造成损害,因此研究恶臭硫化物的性质有重要意义。分析了硫化氢、甲硫醇、乙硫醇、甲硫醚、二甲基二硫等5种含硫气田生产中常见恶臭硫化物的物理性质、对人的生理影响、嗅阈值和职业接触限值,并研究了我国环境标准浓度与嗅阈值和职业接触限值的关系。研究表明,我国环境标准允许排污单位周围存在一定程度的恶臭气味,但满足厂界浓度要求的恶臭气体不会对人员健康造成危害。本研究成果对于认识恶臭硫化物特性、预防职业危害具有借鉴意义。
Odor sulfides in sour gas field will not only pollute the environment, but also may cause damage to mental and physical health of operators, so it is important to study the properties of these gases. Analyzed are physical properties of such typical odor sulfides as hydrogen sulfide, methyl mercaptan, ethyl mercaptan, methanethiol (ME), dimethyl sulfide (DMS) and dimethyl disulfide (DMDS) in the process of sour gas field production, researched are physiological effects and hazards, odor thresholds and occupational exposure limit values and studied is the relationship of concentration of environmental standards in China with such odor thresholds and the occupational exposure limit values. The analysis and study results show that a certain amount of bad odor existing around any pollutant discharging unit is allowable by the Chinese national environmental standard only if its concentration meets relative requirements specified in the Chinese national environmental standard and has no harm to physical health. The research achievement is useful to understand the stench sulfide characteristics and prevent occupational hazards.